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南、北极雪、冰、水中的痕量元素离子与水汽化学
刘明星1,2, 顾宏堪1,2
1.中国科学院海洋研究所 青岛;266071
摘要:
应用水汽化学的方法学和理论,研究南、北极雪、冰、水中的Zn2+等离子。南、北极雪、冰、水中Zn2+,Cd2+,Pb2+,Cu2+,Sn4+,Bi3+离子含量的空间变化很小,与水汽化学原理计算的离子总平均含量Zn2+ 5.0μg/L,Ch2+ 0.080 μg/L,Pb2+ 0.030μg/L,Cu2+ 0.70μg/L,Sn4+ 0.99μg/L,Bi3+ 0.18μg/L相一致.南北极Zn2+等离子处于自然本底浓度,并处于天然水循环之中。
关键词:  南、北极雪  痕量元素  水汽化学
DOI:
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基金项目:国家自然科学基金资助项目,49576290号
ION OF SOME TRACE ELEMENTS IN ANTARCTIC AND ARCTIC SNOW, ICE AND WATER BASED UPON WATER VAPORCHEMISTRY TECHNIQUES
LIU Ming-xing,GU Hong-kan
Institute of Oceanology,The Chinese Academy of Sciences,Qingdao,266071
Abstract:
The some trace elements in the Antarctic and Arctic snow, ice, water were studied using the methodology and theory of water vapor chemistry. The concentrations of ions Zn2+,Cd2+,Pb2+, Cu2+, Sn4+ and Bi3+ in Antarctic and Arctic snow show a significant spatial similarity; they are also close to those defined elsewhere on the basis of the studies of water vapor chemistry: on average Zn2+ 5.0 μg/L, Cd2+ 0.080 μg/L, Pb2+ 0.030 μg/L, Cu2+ 0.70 μg/L, Sn4+ 0.99 μg/L, Bi3+ 0.18 μg/L. Apparently, the ion concentrations in the Antarctic and Arctic regions represent natural baseline values and are controlled by natural water cycles.
Key words:  Antarctic and Arctic snow, Trace element ions, Water vapor chemistry
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